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Thread Statistics | Show CCP posts - 2 post(s) |
Skydell
Caldari Space Mermaids
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Posted - 2011.06.13 05:25:00 -
[151]
Who smells like baby powder? Buy some real deoderant you cheap SOB. |
Clyde ElectraGlide
Gallente Center for Advanced Studies
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Posted - 2011.06.13 07:05:00 -
[152]
In synthetic chemistry, two classes of chlorination are usually of interest. Oxidative chlorinations entail the transfer of Cl2 from the reagent to the substrate. Substitutive chlorinations entail replacement of O or OH groups with chloride. PCl5 can be used for both processes.
PCl5 will convert carboxylic acids to the corresponding acyl chloride as well as alcohols to alkyl chloride. Thionyl chloride is more commonly used in the laboratory because the SO2 is more easily separated from the organic products than is POCl3.
PCl5 and PCl3 bear some resemblance to SO2Cl2, as both serve often as sources of Cl2. Again for oxidative chlorinations on the laboratory scale, SO2Cl2 is often preferred over PCl5 since the gaseous SO2 by-product is readily separated.
PCl5 reacts with a tertiary amides, such as DMF, to give dimethylchloromethyleneammonium chloride, which is called the Vilsmeier reagent, [(CH3)2NCClH]Cl. More typically, a related salt is generated from the reaction of DMF and POCl3. Such reagents are useful in the preparation of derivatives of benzaldehyde by formylation and for the conversion of C-OH groups into C-Cl groups.
In contrast to PCl3, the pentachloride replaces allylic and benzylic CH bonds and is especially renowned for the conversion of C=O groups to CCl2 groups.
The electrophilic character of PCl5 is highlighted by its reaction with styrene to give, after hydrolysis, phosphonic acid derivatives.
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Halcyon Ingenium
Caldari Bene Gesserit ChapterHouse Sanctuary Pact
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Posted - 2011.06.13 07:55:00 -
[153]
I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. I am Jack's total lack of surprise. On the other hand has anyone really been far even as decided to use even go want to do look more like? ________________________________________________
Huh? |
Cpt Fina
Red Dwarf Mining Corporation space weaponry and trade
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Posted - 2011.06.13 08:02:00 -
[154]
Edited by: Cpt Fina on 13/06/2011 08:02:26
Edited for grammar
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Lost Hamster
Hamster Holding Corp
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Posted - 2011.06.13 08:45:00 -
[155]
Posting in this awesome thread.
*IBTL* -------------------------------------------------------------------------------------------- Shields are like pants, they're supposed to come off. Armor is like the condom once its gone ur ****ed |
MotherMoon
Huang Yinglong
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Posted - 2011.06.13 08:46:00 -
[156]
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Goremageddon Box
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Posted - 2011.06.13 09:08:00 -
[157]
Originally by: Lost Hamster Posting in this awesome thread.
*IBTL*
get back on that treadmill _______________________ Hottest Character Ever. |
baltec1
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Posted - 2011.06.13 09:15:00 -
[158]
Edited by: baltec1 on 13/06/2011 09:16:26
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Akita T
Caldari Navy Volunteer Task Force
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Posted - 2011.06.13 10:50:00 -
[159]
_
Make ISK||Build||React||1k papercuts
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Spurty
Caldari V0LTA VOLTA Corp
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Posted - 2011.06.13 10:55:00 -
[160]
Fake edit to fix typos
Did my post force you to resort to a meme as a reply? Congrats, you're a moron.
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andeira
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Posted - 2011.06.13 11:06:00 -
[161]
-------------
Originally by: Stitcher For frak's sake, it took millions of years of evolution for that brain to get inside your skull, would it kill you to actually USE the damned thing?
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Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 11:14:00 -
[162]
Edited by: Evelgrivion on 13/06/2011 11:14:42
Originally by: baltec1 Edited by: baltec1 on 13/06/2011 09:16:26
Those last four panels, every time...
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Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 11:25:00 -
[163]
And once more for D'awww.
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Lakut
Nobody expects the Spanish Inquisition
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Posted - 2011.06.13 11:28:00 -
[164]
Someone said ponies?
Most importantly, the issue is that this is already my signature. ---------- You get a wonderful view from the point of no return. |
Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 11:32:00 -
[165]
I see your Tyrant Celestia and raise you some in-character Celestia!
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Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 11:38:00 -
[166]
Luna bump
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Sader Rykane
Amarr Midnight Sentinels Midnight Space Syndicate
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Posted - 2011.06.13 11:40:00 -
[167]
****.... I don't think I'm doin it rite.
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Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 11:42:00 -
[168]
Originally by: Sader Rykane ****.... I don't think I'm doin it rite.
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Illwill Bill
Talu Shaya Talu Shaya Empire
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Posted - 2011.06.13 11:43:00 -
[169]
Those ponies make me feel funny inside.
Originally by: CCP Zymurgist Revenge is a dish best served with auto-cannons.
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Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 11:45:00 -
[170]
Originally by: Illwill Bill Those ponies make me feel funny inside.
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Rover Vitesse
Gallente FinFleet Raiden.
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Posted - 2011.06.13 11:46:00 -
[171]
Mission-type tactics (German: Auftragstaktik, from Auftrag and Taktik; also known as Mission Command in the US and UK), have (arguably) been a central component of the tactics of German armed forces since the 19th century. The term Auftragstaktik was coined by opponents of the development of mission-type tactics. Opponents of implementation mission-type tactics were called Normaltaktiker.
In mission-type tactics, the military commander gives their subordinate leaders a clearly defined goal (the mission), the forces needed to accomplish that goal and a time frame within which the goal must be reached. The subordinate leaders then implement the order independently. The subordinate leader is given, to a large extent, the planning initiative and a freedom in execution which allows a high-degree of flexibility at the Operational and Tactical levels of command. Mission-type Orders free the higher leadership from tactical details.
For the success of the mission-type tactics it is especially important that the subordinate leaders understand the intent of the orders and are given proper guidance and that they are trained so they can act independently. In contrast to the mission-type tactics is Command and control used by U.S. armed forces. The success of the doctrine rests upon the receiver of orders understanding the intent of the issuer of the orders and acting to achieve their goal even if their actions violated other guidance or orders they had received. Clearly taking the risks of violating other previously expressed limitations as a routine step to achieving a mission is a behaviour most easily sustained in a particular type of innovative culture. That culture is often one associated today with elite units and not a whole army.
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Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 11:48:00 -
[172]
Originally by: Rover Vitesse Mission-type tactics (German: Auftragstaktik, from Auftrag and Taktik; also known as Mission Command in the US and UK), have (arguably) been a central component of the tactics of German armed forces since the 19th century. The term Auftragstaktik was coined by opponents of the development of mission-type tactics. Opponents of implementation mission-type tactics were called Normaltaktiker.
In mission-type tactics, the military commander gives their subordinate leaders a clearly defined goal (the mission), the forces needed to accomplish that goal and a time frame within which the goal must be reached. The subordinate leaders then implement the order independently. The subordinate leader is given, to a large extent, the planning initiative and a freedom in execution which allows a high-degree of flexibility at the Operational and Tactical levels of command. Mission-type Orders free the higher leadership from tactical details.
For the success of the mission-type tactics it is especially important that the subordinate leaders understand the intent of the orders and are given proper guidance and that they are trained so they can act independently. In contrast to the mission-type tactics is Command and control used by U.S. armed forces. The success of the doctrine rests upon the receiver of orders understanding the intent of the issuer of the orders and acting to achieve their goal even if their actions violated other guidance or orders they had received. Clearly taking the risks of violating other previously expressed limitations as a routine step to achieving a mission is a behaviour most easily sustained in a particular type of innovative culture. That culture is often one associated today with elite units and not a whole army.
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Alara IonStorm
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Posted - 2011.06.13 11:50:00 -
[173]
Edited by: Alara IonStorm on 13/06/2011 11:53:13
Originally by: Rover Vitesse Mission-type tactics (German: Auftragstaktik, from Auftrag and Taktik; also known as Mission Command in the US and UK), have (arguably) been a central component of the tactics of German armed forces since the 19th century. The term Auftragstaktik was coined by opponents of the development of mission-type tactics. Opponents of implementation mission-type tactics were called Normaltaktiker.
In mission-type tactics, the military commander gives their subordinate leaders a clearly defined goal (the mission), the forces needed to accomplish that goal and a time frame within which the goal must be reached. The subordinate leaders then implement the order independently. The subordinate leader is given, to a large extent, the planning initiative and a freedom in execution which allows a high-degree of flexibility at the Operational and Tactical levels of command. Mission-type Orders free the higher leadership from tactical details.
For the success of the mission-type tactics it is especially important that the subordinate leaders understand the intent of the orders and are given proper guidance and that they are trained so they can act independently. In contrast to the mission-type tactics is Command and control used by U.S. armed forces. The success of the doctrine rests upon the receiver of orders understanding the intent of the issuer of the orders and acting to achieve their goal even if their actions violated other guidance or orders they had received. Clearly taking the risks of violating other previously expressed limitations as a routine step to achieving a mission is a behaviour most easily sustained in a particular type of innovative culture. That culture is often one associated today with elite units and not a whole army.
This Thread is now ABOUT PONIES ALL OTHER MEMES DEAD!
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Sader Rykane
Amarr Midnight Sentinels Midnight Space Syndicate
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Posted - 2011.06.13 11:54:00 -
[174]
Originally by: Alara IonStorm
This Thread is now ABOUT PONIES ALL OTHER MEMES DEAD!
Pretty sure this thread is officially beyond conventional definitions.
This thread is.... The Internet in all its grimy. smelly, rancid glory. This thread can be everything, and anything. It's the only thread I know of that could handle both ponies and....Belgian Waffles.
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Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 11:56:00 -
[175]
Edited by: Evelgrivion on 13/06/2011 11:56:04
Originally by: Sader Rykane
Originally by: Alara IonStorm
This Thread is now ABOUT PONIES ALL OTHER MEMES DEAD!
Pretty sure this thread is officially beyond conventional definitions.
This thread is.... The Internet in all its grimy. smelly, rancid glory. This thread can be everything, and anything. It's the only thread I know of that could handle both ponies and....Belgian Waffles.
I think you mean Carrot Top!
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Illwill Bill
Talu Shaya Talu Shaya Empire
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Posted - 2011.06.13 11:56:00 -
[176]
Edited by: Illwill Bill on 13/06/2011 11:56:52
Originally by: Sader Rykane
Do want
Edit:
amidoinitrie?
Originally by: CCP Zymurgist Revenge is a dish best served with auto-cannons.
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Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 12:00:00 -
[177]
Originally by: Illwill Bill
amidoinitrie?
Yes you are.
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Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 12:05:00 -
[178]
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Alara IonStorm
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Posted - 2011.06.13 12:07:00 -
[179]
Originally by: Sader Rykane This thread is.... The Internet in all its grimy. smelly, rancid glory. This thread can be everything, and anything. It's the only thread I know of that could handle both ponies and....Belgian Waffles.
Like Imagination Land...
Cept you can never unsee what others have imagined.
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Evelgrivion
Gunpoint Diplomacy
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Posted - 2011.06.13 12:12:00 -
[180]
Fluttershy is here to bring you a special message.
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